Development of siloxane-based amphiphiles as cell stabilizers for porous shape memory polymer systems.

ABSTRACT:

Hypothesis

Polyurethane foaming surfactants are cell stabilized at the polymer-gas interface during foam blowing to prevent bubble coalescence. Siloxane-based surfactants are typically used to generate a surface tension gradient at the interface. The chemical structure of the hydrophobic and hydrophilic units affects surfactant properties, which can further influence foam morphology.

Experiments

Siloxane-polyethylene glycol (PEG) ether amphiphiles were synthesized in high yield via hydrosilylation to serve as surfactants for shape memory polymer (SMP) foams. Hydrophobic units consisted of trisiloxane and polydimethyl siloxane, and PEG allyl methyl ether (n=8 or 25) was the hydrophilic component. Upon confirming successful synthesis of the surfactants, their surface tension w

SUBMITTER: Hasan SM 

PROVIDER: S-EPMC5841088 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature