A metal-organic framework with ultrahigh glass-forming ability.

ABSTRACT: Glass-forming ability (GFA) is the ability of a liquid to avoid crystallization during cooling. Metal-organic frameworks (MOFs) are a new class of glass formers (1-3), with hitherto unknown dynamic and thermodynamic properties. We report the discovery of a new series of tetrahedral glass systems, zeolitic imidazolate framework-62 (ZIF-62) [Zn(Im_2-x bIm _x )], which have ultrahigh GFA, superior to any other known glass formers. This ultrahigh GFA is evidenced by a high viscosity η (10⁵ Pa·s) at the melting temperature T_m, a large crystal-glass network density deficit (Δρ/ρ_g)_network, no crystallization in supercooled region on laboratory time scales, a low fragility (m = 23), an extreme

SUBMITTER: Qiao A 

PROVIDER: S-EPMC5844704 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature