Chirality-controlled spontaneous twisting of crystals due to thermal topochemical reaction.

ABSTRACT: Crystals that show mechanical response against various stimuli are of great interest. These stimuli induce polymorphic transitions, isomerizations, or chemical reactions in the crystal and the strain generated between the daughter and parent domains is transcribed into mechanical response. We observed that the crystals of modified dipeptide LL (N₃-l-Ala-l-Val-NHCH₂C≡CH) undergo spontaneous twisting to form right-handed twisted crystals not only at room temperature but also at 0 °C over time. Using various spectroscopic techniques, we have established that the twisting is due to the spontaneous topochemical azide-alkyne cycloaddition (TAAC) reaction at room temperature or lower temperatures. The rate of twisting can be increased by heating, exploiting the faster kineti

SUBMITTER: Rai R 

PROVIDER: S-EPMC5866578 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature