Exciton coupling in diketopyrrolopyrrole-helicene derivatives leads to red and near-infrared circularly polarized luminescence.

ABSTRACT: Molecular and macromolecular chiral π-conjugated diketopyrrolopyrrole (DPP)-helicene derivatives were prepared and their chiroptical properties examined experimentally and theoretically. Exciton coupling leads to red and near-infrared circularly polarized absorption and luminescence arising from the achiral DPP units in the helical environment, highlighting an interesting synergy between the chiral helicene and the organic dye.

SUBMITTER: Dhbaibi K 

PROVIDER: S-EPMC5872492 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature