Observational constraints on glyoxal production from isoprene oxidation and its contribution to organic aerosol over the Southeast United States.

ABSTRACT: We use a 0-D photochemical box model and a 3-D global chemistry-climate model, combined with observations from the NOAA Southeast Nexus (SENEX) aircraft campaign, to understand the sources and sinks of glyoxal over the Southeast United States. Box model simulations suggest a large difference in glyoxal production among three isoprene oxidation mechanisms (AM3ST, AM3B, and MCM v3.3.1). These mechanisms are then implemented into a 3-D global chemistry-climate model. Comparison with field observations shows that the average vertical profile of glyoxal is best reproduced by AM3ST with an effective reactive uptake coefficient γ_glyx of 2 × 10^-3, and AM3B without heterogeneous loss of glyoxal. The two mechanisms lead to 0-0.8 μg m^-3 secondary organic aerosol (SOA)

SUBMITTER: Li J 

PROVIDER: S-EPMC5880315 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature