Optimal Electrocatalytic Pd/MWNTs Nanocatalysts toward Formic Acid Oxidation.

ABSTRACT: The operating conditions such as composition of electrolyte and temperature can greatly influence the formic acid (HCOOH) oxidation reaction (FAOR). Palladium decorated multi-walled carbon nanotubes (Pd/MWNTs) were successfully synthesized and employed as nanocatalysts to explore the effects of formic acid, sulfuric acid (H₂SO₄) concentration and temperature on FAOR. Both the hydrogen adsorption in low potential range and the oxidation of poisoning species during the high potential range in cyclic voltammetry were demonstrated to contribute to the enhanced electroactivity of Pd/MWNTs. The as-synthesized Pd/MWNTs gave the best performance under a condition with balanced adsorptions of HCOOH and H₂SO₄ molecules. The dominant dehydrogenation pathway

SUBMITTER: Wang Y 

PROVIDER: S-EPMC5881920 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature