Molecular excitonic seesaws.

ABSTRACT: The breaking of molecular symmetry through photoexcitation is a ubiquitous but rather elusive process, which, for example, controls the microscopic efficiency of light harvesting in molecular aggregates. A molecular excitation within a π-conjugated segment will self-localize due to strong coupling to molecular vibrations, locally changing bond alternation in a process which is fundamentally nondeterministic. Probing such symmetry breaking usually relies on polarization-resolved fluorescence, which is most powerful on the level of single molecules. Here, we explore symmetry breaking by designing a large, asymmetric acceptor-donor-acceptor (A₁-D-A₂) complex 10 nm in length, where excitation energy can flow from the donor, a π-conjugated oligomer, to either one of the tw

SUBMITTER: Wilhelm P 

PROVIDER: S-EPMC5910862 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature