Triplet state homoaromaticity: concept, computational validation and experimental relevance.

ABSTRACT: Cyclic conjugation that occurs through-space and leads to aromatic properties is called homoaromaticity. Here we formulate the homoaromaticity concept for the triplet excited state (T₁) based on Baird's 4n rule and validate it through extensive quantum-chemical calculations on a range of different species (neutral, cationic and anionic). By comparison to well-known ground state homoaromatic molecules we reveal that five of the investigated compounds show strong T₁ homoaromaticity, four show weak homoaromaticity and two are non-aromatic. Two of the compounds have previously been identified as excited state intermediates in photochemical reactions and our calculations indicate that they are also homoaromatic in the first singlet excited state. Homoaromaticity sho

SUBMITTER: Jorner K 

PROVIDER: S-EPMC5916107 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature