Readily accessible shape-memory effect in a porous interpenetrated coordination network.

ABSTRACT: Shape-memory effects are quite well-studied in general, but there is only one reported example in the context of porous materials. We report the second example of a porous coordination network that exhibits a sorbate-induced shape-memory effect and the first in which multiple sorbates, N₂, CO₂ and CO promote this effect. The material, a new threefold interpenetrated pcu network, [Zn₂(4,4'-biphenyldicarboxylate)₂(1,4-bis(4-pyridyl)benzene)]_n (X-pcu-3-Zn-3i), exhibits three distinct phases: the as-synthesized α phase; a denser-activated β phase; and a shape-memory γ phase, which is intermediate in density between the α and β phases. The γ phase is kinetically stable over multiple adsorption/desorption cycles and only reverts to the β pha

SUBMITTER: Shivanna M 

PROVIDER: S-EPMC5922793 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature