Polymorphism of terthio-phene with surface confinement.

ABSTRACT: The origin of unknown polymorphic phases within thin films is still not well understood. This work reports on crystals of the molecule terthio-phene which were grown by thermal gradient crystallization using glass-plate substrates. The crystalline domains displayed a plate-like morphology with an extended lateral size of about 100 µm, but a thickness of only a few µm. Specular X-ray diffraction patterns confirmed the presence of a new polymorph of terthio-phene. Crystal structure solution from a single crystal peeled from the film revealed a structure with an extremely large unit-cell volume containing 42 independent molecules. In contrast to the previously determined crystal structure of terthio-phene, a herringbone packing motif was observed where the terminal ends of the molecules are a

SUBMITTER: Resel R 

PROVIDER: S-EPMC5929376 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature