Porous aromatic framework with mesopores as a platform for a super-efficient heterogeneous Pd-based organometallic catalysis.

ABSTRACT: A strategy using a mesoporous amine-tagged porous aromatic framework (PAF70-NH₂ ) to immobilize a palladium (Pd)-based molecular catalyst has been developed. The resulting immobilized catalyst PAF70-Pd, in which the framework is entirely constructed by phenyl rings linked with stable carbon-carbon bonds, has high structural rigidity and stability. Compared with the known porous organic material immobilized Pd-based catalysts, PAF70-Pd has the highest Pd content so far. Moreover, PAF70-Pd has extremely high catalytic activity with good size selectivity and very easy recyclability in catalyzing the Suzuki-Miyaura coupling reaction. In the current system, the catalyst loading could be as low as 0.001 mol% and the TOF value could go up to 28 800 h^-1<

SUBMITTER: Jing LP 

PROVIDER: S-EPMC5934748 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature