De novo design of D-σ-A molecules as universal hosts for monochrome and white phosphorescent organic light-emitting diodes.

ABSTRACT: Two novel D-σ-A host materials 11,11-bis(9-phenyl-9H-carbazol-3-yl)-11H-benzo[4,5]imidazo[1,2-a]indole (BII-BCz) and 4,4'-(11H-benzo[4,5]imidazo[1,2-a]indole-11,11-diyl)bis(N,N-diphenylaniline) (BII-TPA) are synthesized by using the sp³ carbon attached to a newly designed 11H-benzo[4,5]imidazo[1,2-a]indole building block to link two electron-donating groups. The resulting materials feature high triplet energy levels, good thermal properties and suitable photophysical properties as universal hosts for full-color phosphorescent organic light-emitting diodes (OLEDs). Both BII-BCz and BII-TPA reveal excellent performances in blue, green, yellow, orange and red phosphorescent OLEDs with the same device structure. The empl

SUBMITTER: Chen WC 

PROVIDER: S-EPMC5935058 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature