cis-Oxoruthenium complexes supported by chiral tetradentate amine (N₄) ligands for hydrocarbon oxidations.

ABSTRACT: We report the first examples of ruthenium complexes cis-[(N₄)Ru^IIICl₂]⁺ and cis-[(N₄)Ru^II(OH₂)₂]²⁺ supported by chiral tetradentate amine ligands (N₄), together with a high-valent cis-dioxo complex cis-[(N₄)Ru^VI(O)₂]²⁺ supported by the chiral N₄ ligand mcp (mcp = N,N'-dimethyl-N,N'-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine). The X-ray crystal structures of cis-[(mcp)Ru^IIICl₂](ClO₄) (1a), cis-[(Me₂mcp)Ru^IIICl₂]ClO₄ (2a) and cis-[(pdp)Ru^IIICl_2<

SUBMITTER: Tse CW 

PROVIDER: S-EPMC5943683 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature