Crystal structures of 5,12-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-decane cobalt(III) mono-phenyl-acetyl-ide and bis-phenyl-acetyl-ide.

ABSTRACT: Reported in this contribution are the synthesis and crystal structures of new mono- and bis-phenyl-acetyl-ides based on Co^III(DMC) (DMC is 5,12-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne). Chlorido-(5,12-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne)(phenyl-ethyn-yl)cobalt(III) chloride-aceto-nitrile-methanol (1/1/1), [Co(C₈H₅)Cl(C₁₂H₂₈N₄)]Cl·CH₃CN·CH₃OH, 1, and (5,12-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne)bis-(phenyl-ethyn-yl)cobalt(III) tri-fluoro-methane-sulfonate-di-chloro-methane (2/1), [Co(C₈H₅)₂(C₁₂H₂₈N₄)]₂(CF₃SO₃)₂·CH₂Cl₂, 2, were prepa

SUBMITTER: Oxley BM 

PROVIDER: S-EPMC5946981 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature