Tris[2,2,6,6-tetra-methyl-8-(tri-methyl-sil-yl)benzo[1,2-d;4,5-d']bis-(1,3-di-thiol)-4-yl]methanol diethyl ether monosolvate.

ABSTRACT: The title compound, a tri-aryl-methanol, C₄₆H₆₄OS₁₂Si₃1, was synthesized via li-thia-tion of tris-2,2,6,6-tetra-methyl-benzo[1,2-d;4,5-d']bis-[1,3]di-thiol-4-yl-methanol, 2, and electrophilic quenching with tri-methyl-silyl chloride. The current crystal structure reveals information about the reactivity of this compound and compares well with the structure reported for the unsubstituted parent compound 2 [Driesschaert et al. (2012 ▸). Eur. J. Org. Chem.33, 6517-6525]. The title compound 1 forms mol-ecular propellers and crystallizes in P [Formula: see text], featuring an unusually long Si-C_ar bond of 1.910 (3) Å. Moreover, the geometry at the central quaternar

SUBMITTER: Fleck N 

PROVIDER: S-EPMC5946984 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature