ABSTRACT: The bulky tris(3-tert-butyl-5-pyrazolyl)hydroborato ligand, [TpBut,Me], has been employed to obtain the first structurally characterized example of a molecular magnesium compound that features a terminal fluoride ligand, namely [TpBut,Me]MgF, via the reaction of [TpBut,Me]MgMe with Me3SnF. The chloride, bromide and iodide complexes, [TpBut,Me]MgX (X = Cl, Br, I), can also be obtained by an analogous method using Me3SnX. The molecular structures of the complete series of halide derivatives, [TpBut,Me]MgX (X = F, Cl, Br, I) have been determined by X-ray diffraction. In each case, the Mg-X bond lengths are shorter than the sum of the covalent radii, thereby indicating that there is a significant ionic component to the bonding, in agreement with density functional theory calculations. The fluo
