Control of cerium oxidation state through metal complex secondary structures.

ABSTRACT: A series of alkali metal cerium diphenylhydrazido complexes, M _x (py) _y [Ce(PhNNPh)₄], M = Li, Na, and K, x = 4 (Li and Na) or 5 (K), and y = 4 (Li), 8 (Na), or 7 (K), were synthesized to probe how a secondary coordination sphere would modulate electronic structures at a cerium cation. The resulting electronic structures of the heterobimetallic cerium diphenylhydrazido complexes were found to be strongly dependent on the identity of the alkali metal cations. When M = Li⁺ or Na⁺, the cerium(iii) starting material was oxidized with concomitant reduction of 1,2-diphenylhydrazine to aniline. Reduction of 1,2-diphenylhydrazine was not observed when M = K⁺, and the complex remained in the cerium(iii) ox

SUBMITTER: Levin JR 

PROVIDER: S-EPMC5951102 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature