Supramolecular aggregates of single-molecule magnets: exchange-biased quantum tunneling of magnetization in a rectangular [Mn₃]₄ tetramer.

ABSTRACT: The syntheses and properties of four magnetically-supramolecular oligomers of triangular Mn₃ units are reported: dimeric [Mn₆O₂(O₂CMe)₈(CH₃OH)₂(pdpd)₂] (3) and [Mn₆O₂(O₂CMe)₈(py)₂(pdpd)₂](ClO₄)₂ (4), and tetrameric [Mn₁₂O₄(O₂CR)₁₂(pdpd)₆](ClO₄)₄ (R = Me (5), ^t Bu (6)). They were all obtained employing 3-phenyl-1,5-di(pyridin-2-yl)pentane-1,5-dione dioxime (pdpdH₂), either in direct synthesis reactions involving oxidation of Mn^II salts or in metathesis reactions with the pref

SUBMITTER: Nguyen TN 

PROVIDER: S-EPMC5952871 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature