Structure cristalline, caracterisation spectroscopique, calcul DFT et analyse de surface Hirshfeld du perchlorate de p-toluidinium.

ABSTRACT: The synthesis of p-toluidinium perchlorate (systematic name: 4-methyl-anilinium perchlorate), C₇H₁₀N⁺·ClO₄^-, was carried out from an aqueous reaction of perchloric acid with p-toluidine. This compound was characterized by powder XRD, IR and UV-Vis spectroscopy. The structure was further confirmed by a single-crystal X-ray diffraction study. The crystal structure is formed by a succession of two-dimensional mol-ecular layers consisting of perchlorate anions and organic cations parallel to the (100) plane and located at x = 2n + ½ (n ∈ Z). Each mixed layer is formed by infinite chains {C₇H₁₀N⁺·ClO₄^-} _n parallel to the [010]

SUBMITTER: Ben Jomaa M 

PROVIDER: S-EPMC5956314 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature