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The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di-methyl-hydrazin-1-yl-idene)meth-yl]-1'-(di-phenyl-phospho-rothio-yl)ferrocene.

ABSTRACT: The asymmetric unit of the title compound, [Fe(C8H11N2)(C17H14PS)], contains two independent mol-ecules (A and B) with very similar conformations. Each mol-ecule is built up from a ferrocene unit substituted in the 1 and 1' positions by a protected sulfur di-phenyl-phosphine and by a di-methyl-hydrazine, -C(H)=N-N(CH3)2, fragment. The two independent mol-ecules are linked by a C-H⋯N hydrogen bond. In the crystal, the A-B dimer is linked by a pair of C-H⋯S hydrogen bonds, forming a centrosymmetric four-mol-ecule arrangement. These units are linked by C-H⋯π inter-actions, forming a supra-molecular three-dimensional structure.

SUBMITTER: Mouas TN

PROVIDER: S-EPMC5956322 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

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The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di-methyl-hydrazin-1-yl-idene)meth-yl]-1'-(di-phenyl-phospho-rothio-yl)ferrocene.

Mouas Toma Nardjes TN Daran Jean-Claude JC Merazig Hocine H Manoury Eric E

Acta crystallographica. Section E, Crystallographic communications 20180112 Pt 2

The asymmetric unit of the title compound, [Fe(C8H11N2)(C17H14PS)], contains two independent mol-ecules (A and B) with very similar conformations. Each mol-ecule is built up from a ferrocene unit substituted in the 1 and 1' positions by a protected sulfur di-phenyl-phosphine and by a di-methyl-hydrazine, -C(H)=N-N(CH3)2, fragment. The two independent mol-ecules are linked by a C-H⋯N hydrogen bond. In the c ...[more]

PMID: 29850039

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