A new cadmium coordination polymer based on 4-amino-4H-1,2,4-triazole.

ABSTRACT: A new cadmium coordination polymer, poly[bis-(4-amino-4H-1,2,4-triazolium) [bis-(μ₂-4-amino-4H-1,2,4-triazole-κ²N¹:N²)tetra-μ₂-chlorido-tetra-chlorido-tri-cad-mium(II)] dihydrate], {(C₂H₅N₄)₂[Cd₃Cl₈(C₂H₄N₄)₂]·2H₂O} _n , was synthesized by the reaction of 4-amino-4H-1,2,4 triazole with cadmium(II) chloride in aqueous solution. With an unusual architecture, the crystal structure exhibits two distorted octa-hedral coordinations of Cd^II joined by edge sharing. The first is composed by four chlorine and two N atoms from the triazole ligands. The second is form

SUBMITTER: Said M 

PROVIDER: S-EPMC5956325 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature