Crystal structure of a palladium(II) complex containing the wide bite-angle bis-(selenium) ligand, cis-[( ^t BuNH)(Se)P(μ-N ^t Bu)₂P(Se)(NH ^t Bu)].

ABSTRACT: A palladium(II) complex {systematic name: dichlorido[1,3-di-tert-butyl-2,4-bis(tert-butylamino)-1,3,2λ⁵,4λ⁵-diazadiphosphetidine-2,4-diselone-κ²Se,Se']pal-ladium(II)}, cis-[PdCl₂{I}], (II), containing a bis-(selenium) ligand based on cyclo-diphosph(V)azane, cis-[( ^t BuNH)(Se)P(μ-N ^t Bu)₂P(Se)(NH ^t Bu)], (I), has been synthesized and structurally characterized. The crystal structure of complex II reveals that the ligand chelates through selenium donors with the natural bite-angle of 110.54 (1)° and a Pd-Se bond distance of 2.444 (1) Å. The coordination around Pd^II shows a slightly distorted square-planar

SUBMITTER: Bonnette A 

PROVIDER: S-EPMC5956332 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature