Crystal structure of a new mixed-metal coordin-ation polymer consisting of Ni^II piperidine-di-thio-carbamate and penta-nuclear Cu^I-I cluster units.

ABSTRACT: A new heterometallic Cu^I-Ni^II coordination polymer, poly[[tetra-μ₃-iodido-μ₂-iodido-bis-(μ₃-piperidine-1-di-thio-carbamato)propio-nitrilepenta-copper(I)nickel(II)] chloro-form monosolvate], {[Cu^I₅Ni^III₅(C₆H₁₀NS₂)₂(C₃H₅N)]·CHCl₃} _n , has been synthesized and structurally characterized. This coordination polymer consists of an Ni^II mononuclear unit of Ni^II(Pip-dtc)₂ (Pip-dtc^- is piperidine-1-di-thio-carbamate) and a penta-nuclear copper(I) cluster unit of Cu₅I₅(CH₃CH₂CN). The Ni^II ion, which lies on an i

SUBMITTER: Himoto K 

PROVIDER: S-EPMC5956344 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature