Core-shell zeolite@aqueous miscible organic-layered double hydroxides.

ABSTRACT: We report a general method for the synthesis of core-shell hybrid materials containing a microporous zeolite core with an aqueous miscible organic-layered double hydroxide (AMO-LDH) shell using a simple in situ coprecipitation method. For example, zeolite-HY@AMO-Mg₂Al-CO₃-LDH contains a 150 nm hierarchical AMO-Mg₂Al-CO₃-LDH surface coating on zeolite-HY. It exhibits a similar BET surface area (698 m² g^-1) as the parent zeolite-HY but this surface area has been re-allocated between microspores and mesopores. We believe that surface aluminium sites act as nucleation sites for the formation of the LDH coating and so robustly links it into the zeolite lattice. We expect that this new hybrid structure with micropores domin

SUBMITTER: Chen C 

PROVIDER: S-EPMC5975924 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature