Coordination of 3-Methylindole-Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two-Electron Reduction.

ABSTRACT: We report the coordination chemistry of indole based tripodal tetraphosphine ligands to iron(II), cobalt(II) and nickel(II). These complexes are formed by simple synthetic protocols and were characterized by a combination of spectroscopic techniques and single-crystal X-ray analysis. The molecular structures as determined by X-ray diffraction show that the geometry of the nickel and cobalt complexes are distorted trigonal bipyramidal. The monocationic iron(II) complexes also have distorted trigonal bipyramidal geometries, but the dicationic analogue has an octahedral geometry. Two-electron reduction of the cobalt(+II) and the nickel(+II) complexes in the presence of N₂ did not lead to the coordination of N₂. In contrast, two-electron reduction of the iron(+II) complex

SUBMITTER: van de Watering FF 

PROVIDER: S-EPMC5993305 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature