Synthesis and structure of an aryl-selenenium(II) cation, [C₃₄H₄₁N₄Se⁺]₂[Hg(SeCN)₄]^2-, based on a 5-tert-butyl-1,3-bis-(1-pentyl-1H-benzimidazol-2-yl)benzene scaffold.

ABSTRACT: In the title salt, bis-{[5-tert-butyl-1,3-bis-(1-pentyl-1H-benzimidazol-2-yl)benzene]selenium} tetra-kis-(seleno-cyanato)-mercury, (C₃₄H₄₁N₄Se)₂[Hg(SeCN)₄], the aryl-selenenium cations, [C₃₄H₄₁N₄Se]⁺, are linked through [Hg(SeCN)₄]^2- anions by C-H⋯N hydrogen bonds. In the cation, the geometry around the Se atom in the 5-tert-butyl-1,3-bis-(1-pentyl-1H-benzimidazol-2-yl)benzene scaffold is T-shaped, resulting from the coordination of Se by the C atom of the central aromatic ring and the N atoms of both of the benzimidazole moieties. The trans Se-N bond lengths are almost equal [2.087 (3) and 2.099 (3) Å] and the Se-C bond length is 1.886

SUBMITTER: Rani V 

PROVIDER: S-EPMC6002820 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature