Crystal structures of two new six-coordinate iron(III) complexes with 1,2-bis(diphenyl-phosphane) ligands.

ABSTRACT: Structural characterization of the ionic complexes [FeCl₂(C₂₆H₂₂P₂)₂][FeCl₄]·0.59CH₂Cl₂ or [(dppen)₂FeCl₂][FeCl₄]·0.59CH₂Cl₂ (dppen = cis-1,2-bis-(di-phenyl-phosphane)ethyl-ene, P₂C₂₆H₂₂) and [FeCl₂(C₃₀H₂₄P₂)₂][FeCl₄]·CH₂Cl₂ or [(dpbz)₂FeCl₂][FeCl₄]·CH₂Cl₂ (dpbz = 1,2-bis-(di-phenyl-phosphane)benzene, P₂C₃₀H₂₄) demonstrates trans coordination of two bidentate phosphane ligands (bis-phosphanes) to a single iron(III) center, resulti

SUBMITTER: McNeil DL 

PROVIDER: S-EPMC6002827 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature