Dataset Information

SuFEx Chemistry of Thionyl Tetrafluoride (SOF₄ ) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates.

ABSTRACT: Thionyl tetrafluoride (SOF₄ ) is a valuable connective gas for sulfur fluoride exchange (SuFEx) click chemistry that enables multidimensional linkages to be created via sulfur-oxygen and sulfur-nitrogen bonds. Herein, we expand the available SuFEx chemistry of SOF₄ to include organolithium nucleophiles, and demonstrate, for the first time, the controlled projection of sulfur-carbon links at the sulfur center of SOF₄ -derived iminosulfur oxydifluorides (R¹ -N=SOF₂ ). This method provides rapid and modular access to sulfonimidoyl fluorides (R¹ -N=SOFR² ), another array of versatile SuFEx connectors with readily tunable reactivity of the S-F handle. Divergent connections derived from these valuable sulfonimidoyl fluo

SUBMITTER: Gao B

PROVIDER: S-EPMC6005182 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

SuFEx Chemistry of Thionyl Tetrafluoride (SOF₄ ) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

SuFEx Chemistry of Thionyl Tetrafluoride (SOF4 ) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates.

OmicsDI is part of the ELIXIR infrastructure

Tweets

SuFEx Chemistry of Thionyl Tetrafluoride (SOF₄ ) with Organolithium Nucleophiles: Synthesis of Sulfonimidoyl Fluorides, Sulfoximines, Sulfonimidamides, and Sulfonimidates.