Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts.

ABSTRACT: Four heterotrinuclear complexes containing the ligands 3,5-bis(2-pyridyl)pyrazolate (bpp^-) and 2,2':6',2''-terpyridine (trpy) of the general formula {[Ru^II(trpy)]₂(μ-[M(X)₂(bpp)₂])}(PF₆)₂, where M = Co^II, Mn^II and X = Cl^-, AcO^- (M = Co^II, X = Cl^-: Ru₂Co-Cl₂ ; M = Mn^II, X = Cl^-: Ru₂Mn-Cl₂ ; M = Co^II, X = AcO^-: Ru₂Co-OAc₂ ; M = Mn^II, X = AcO^-: Ru₂Mn-OAc₂ ), have been prepared for the first time. The complexes have been characterized using different spectroscopic techniques

SUBMITTER: Mognon L 

PROVIDER: S-EPMC6006862 | biostudies-literature | 2016 May

REPOSITORIES: biostudies-literature