Heterobimetallic Pd-K carbene complexes via one-electron reductions of palladium radical carbenes.

ABSTRACT: Heterobimetallic Pd-K carbenes featuring Pd-C_carbene-K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp²)P} ^tBuPdI] ([PC(sp²)P] ^tBu = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that can be interrupted in the presence of a donor solvent.

SUBMITTER: Cui P 

PROVIDER: S-EPMC6014298 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature