The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii).

ABSTRACT: The Ce^III/IV couple is useful for many applications in organic, inorganic, and materials chemistry. However, attaining a general method to access both oxidations states through reversible solution redox chemistry remains challenging. Herein we report the synthesis, characterization, and oxidation chemistry of the novel Ce/Li REMB heterochiral diastereomer, 1-Ce(het). The solution exchange processes of 1-RE(het) (RE = Ce and Yb) were investigated to estimate rates of ligand and cation exchange relevant in homochiral and heterochiral frameworks. A detailed mechanistic investigation following the solution dynamics of 1-Ce(het) revealed reactivity controlled both by ligand reorganization and redistribution processes. Ligand reorganization was responsible for the

SUBMITTER: Robinson JR 

PROVIDER: S-EPMC6016327 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature