Photoelectrochemical hydrogen production in water using a layer-by-layer assembly of a Ru dye and Ni catalyst on NiO.

ABSTRACT: Capture and conversion of sunlight into the storable energy carrier H₂ can be achieved through photoelectrochemical water splitting using light-absorbing cathodes and anodes bearing H₂ and O₂ evolving catalysts. Here, we report on the development of a dye-sensitised p-type nickel oxide (NiO) photocathode with a hexaphosphonated Ru(2,2'-bipyridine)₃ based dye (RuP3) and a tetraphosphonated molecular [Ni(P₂N₂)₂]²⁺ type proton reduction catalyst (NiP) for the photoreduction of aqueous protons to H₂. A layer-by-layer deposition approach was employed, using Zr⁴⁺ ions to link the phosphonate units in RuP3 and NiP in a supramolecular assembly on the NiO photoca

SUBMITTER: Gross MA 

PROVIDER: S-EPMC6021778 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature