Stapled helical o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity.

ABSTRACT: ortho-Oligo(phenylene)ethynylenes (o-OPEs) stapled with enantiopure 2,3-dihydroxybutane diethers have highly intense circular dichroism (CD) spectra and excellent circular polarized luminescence (CPL) responses (g_lum values up to 1.1 × 10^-2), which are consistent with homochiral helically folded structures. In the presence of Ag(i), a change in the CPL emission is observed, representing the first example of CPL active small organic molecular emitters, which can be modulated by carbophilic interactions in a reversible manner.

SUBMITTER: Morcillo SP 

PROVIDER: S-EPMC6022022 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature