Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles.

ABSTRACT: The regioselective and enantioselective intermolecular sp³ C-H functionalization of silicon-substituted alkanes was accomplished using Rh₂( S-NTTL)₄ with readily available 1-sulfonyl-1,2,3-triazoles as carbene precursors. These reactions generate a diverse array of stereodefined substituted silaalkanes.

SUBMITTER: Garlets ZJ 

PROVIDER: S-EPMC6035867 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature