Fast Hydrogen Atom Abstraction by a Hydroxo Iron(III) Porphyrazine.

ABSTRACT: A reactive hydroxoferric porphyrazine complex, [(PyPz)Fe^III(OH) (OH₂)]⁴⁺ (1, PyPz = tetramethyl-2,3-pyridino porphyrazine), has been prepared via one-electron oxidation of the corresponding ferrous species [(PyPz)Fe^II(OH₂)₂]⁴⁺ (2). Electrochemical analysis revealed a pH-dependent and remarkably high Fe^III-OH/Fe^II-OH₂ reduction potential of 680 mV vs Ag/AgCl at pH 5.2. Nernstian behavior from pH 2 to pH 8 indicates a one-proton, one-electron interconversion throughout that range. The O-H bond dissociation energy of the Fe^II-OH₂ complex was estimated to be 84 kcal mol^-1. Accordingly, 1 reacts rapidly with a panel of substrates via C-H hydrogen atom tr

SUBMITTER: Gao H 

PROVIDER: S-EPMC6036922 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature