Crystal structure of cis-[1,2-bis-(di-phenyl-phosphan-yl)ethene-κ²P,P']di-chlorido-platinum(II) chloro-form disolvate: a new polymorph.

ABSTRACT: The title compound, [PtCl₂(C₂₆H₂₂P₂)]·2CHCl₃ (I), is the third monoclinic polymorph of this platinum(II) complex involving the bidentate ligand cis-1,2-bis-(di-phenyl-phosphan-yl)ethyl-ene (cis-dppe) [for the others, see: Oberhauser et al. (1998a ▸). Inorg. Chim. Acta, 274, 143-154, and Oberhauser et al. (1995 ▸). Inorg. Chim. Acta, 238, 35-43]. The structure of compound (I) was solved in the space group P2₁/c, with one complex mol-ecule in the asymmetric unit along with two solvate chloro-form mol-ecules. The Pt^II atom is ligated by two P and two Cl atoms in the equatorial plane and has a perfect square-planar coordination sphere. In the

SUBMITTER: Mugemana J 

PROVIDER: S-EPMC6038620 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature