Crystal structures of (aceto-nitrile-κN)tris-(pyridine-4-thio-amide-κN)bis-(thio-cyanate-κN)cobalt(II) aceto-nitrile disolvate and tetra-kis-(pyridine-4-thio-amide-κN)bis-(thio-cyanate-κN)nickel(II) methanol penta-solvate.

ABSTRACT: Reaction of Co(NCS)₂ or Ni(NCS)₂ with pyridine-4-thio-amide in different solvents led to the formation of two compounds with composition [Co(NCS)₂(C₂H₃N)(C₆H₆N₂S)₃]·2CH₃CN (1) and [Ni(NCS)₂(C₆H₆N₂S)₄]·5CH₃OH (2), respectively. The asymmetric unit of compound 1 consists of one cobalt(II) cation, two thio-cyanate anions, three pyridine-4-thio-amide ligands, one coordinating and two solvate aceto-nitrile mol-ecules. One of the two aceto-nitrile solvate mol-ecules is disordered over two sets of sites in a 0.62:0.38 ratio. The asymmetric unit of compound 2 comprises of one nickel(II) cation, tw

SUBMITTER: Neumann T 

PROVIDER: S-EPMC6038621 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature