Impact of Anions on the Partition Constant, Self-Diffusion, Thermal Stability, and Toxicity of Dicationic Ionic Liquids.

ABSTRACT: Partition constants (K_D^°), molecular dynamics (T₁, T₂, and DOSY measurements), thermal stability, and toxicity of dicationic ionic liquids (ILs) were determined. The dicationic ILs derived from 1,n-bis(3-methylimidazolim-1-yl)octane, [BisOct(MIM)₂][2X] (in which X = Cl, Br, NO₃, SCN, BF₄, and NTf₂), were evaluated to verify the influence of anion structure on the IL properties. A monocationic IL [Oct(MIM)][Br] was also monitored for comparison. In general, the solubility of the ILs followed the anion free energy of hydration (ΔG°_hyd). The thermokinetic and thermodynamic functions of activation of the ILs were determined via thermogravimetric data, and it was

SUBMITTER: Frizzo CP 

PROVIDER: S-EPMC6044912 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature