Fe-N system at high pressure reveals a compound featuring polymeric nitrogen chains.

ABSTRACT: Poly-nitrogen compounds have been considered as potential high energy density materials for a long time due to the large number of energetic N-N or N=N bonds. In most cases high nitrogen content and stability at ambient conditions are mutually exclusive, thereby making the synthesis of such materials challenging. One way to stabilize such compounds is the application of high pressure. Here, through a direct reaction between Fe and N₂ in a laser-heated diamond anvil cell, we synthesize three ironnitrogen compounds Fe₃N₂, FeN₂ and FeN₄. Their crystal structures are revealed by single-crystal synchrotron X-ray diffraction. Fe₃N₂, synthesized at 50 GPa, is isostructural to chromium carbide Cr₃C₂.

SUBMITTER: Bykov M 

PROVIDER: S-EPMC6048061 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature