Efficient cleavage of aryl ether C-O linkages by Rh-Ni and Ru-Ni nanoscale catalysts operating in water.

ABSTRACT: Bimetallic Ru-Ni and Rh-Ni nanocatalysts coated with a phase transfer agent efficiently cleave aryl ether C-O linkages in water in the presence of hydrogen. For dimeric substrates with weaker C-O linkages, i.e. α-O-4 and β-O-4 bonds, low loadings of the precious metal (Rh or Ru) in the nanocatalysts quantitatively afford monomers, whereas for the stronger 4-O-5 linkage higher amounts of the precious metal are required to achieve complete conversion. Under the optimized, relatively mild operating conditions, the C-O bonds in a range of substituted ether compounds are efficiently cleaved, and mechanistic insights into the reaction pathways are provided. This work paves the way to sustainable approaches for the hydrogenolysis of C-O bonds.

SUBMITTER: Bulut S 

PROVIDER: S-EPMC6049526 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature