Weak interactions but potent effect: tunable mechanoluminescence by adjusting intermolecular C-H···π interactions.

ABSTRACT: A new mechanoluminescent material (4-(diphenylamino)phenyl)(4-(diphenylphosphanyl)phenyl)methanone (CDpP), which displays tunable mechanoluminescent emission colors, has been designed and successfully synthesized. CDpP shows two distinct mechanoluminescent colors (blue and green) in different crystalline states. Single-crystal analyses and femtosecond transient emission studies reveal that the striking tunable mechanoluminescence properties of CDpP mainly originate from the different C-H···π interactions in the crystal structures. CDpP crystals with more C-H···π interactions show blue mechanoluminescence (ML), and the emission is attributed to the locally excited (LE)-state because the twisting process for the excited state is restricted by C-H···π interactions. Conversely, CDpP crystals w

SUBMITTER: Xie Z 

PROVIDER: S-EPMC6050600 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature