Ultrahigh Power Factor in Thermoelectric System Nb_0.95M_0.05FeSb (M = Hf, Zr, and Ti).

ABSTRACT: Conversion efficiency and output power are crucial parameters for thermoelectric power generation that highly rely on figure of merit ZT and power factor (PF), respectively. Therefore, the synergistic optimization of electrical and thermal properties is imperative instead of optimizing just ZT by thermal conductivity reduction or just PF by electron transport enhancement. Here, it is demonstrated that Nb_0.95Hf_0.05FeSb has not only ultrahigh PF over ≈100 µW cm^-1 K^-2 at room temperature but also the highest ZT in a material system Nb_0.95M_0.05FeSb (M = Hf, Zr, Ti). It is found that Hf dopant is capable to simultaneously supply carriers for mobility optimization and introduce atomic disorder for reducing lat

SUBMITTER: Ren W 

PROVIDER: S-EPMC6051200 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature