Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters.

ABSTRACT: Converting biomass-based feedstocks into polymers not only reduces our reliance on fossil fuels, but also furnishes multiple opportunities to design biorenewable polymers with targeted properties and functionalities. Here we report a series of high glass transition temperature (T_g up to 184 °C) polyesters derived from sugar-based furan derivatives as well as a joint experimental and theoretical study of substituent effects on their thermal properties. Surprisingly, we find that polymers with moderate steric hindrance exhibit the highest T_g values. Through a detailed Ramachandran-type analysis of the rotational flexibility of the polymer backbone, we find that additional steric hindrance does not necessarily increase chain stiffness in these polyesters. We attribute th

SUBMITTER: Yu X 

PROVIDER: S-EPMC6056526 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature