In situ topographical chemical and electrical imaging of carboxyl graphene oxide at the nanoscale.

ABSTRACT: Visualising the distribution of structural defects and functional groups present on the surface of two-dimensional (2D) materials such as graphene oxide challenges the sensitivity and spatial resolution of the most advanced analytical techniques. Here we demonstrate mapping of functional groups on a carboxyl-modified graphene oxide (GO-COOH) surface with a spatial resolution of ≈10 nm using tip-enhanced Raman spectroscopy (TERS). Furthermore, we extend the capability of TERS by measuring local electronic properties in situ, in addition to the surface topography and chemical composition. Our results reveal that the Fermi level at the GO-COOH surface decreases as the I_D/I_G ratio increases, correlating the local defect density with the Fermi level at nanometre length-sca

SUBMITTER: Su W 

PROVIDER: S-EPMC6056528 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature