Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect.

ABSTRACT: First-order magnetic transitions (FOMTs) with a large discontinuity in magnetization are highly sought in the development of advanced functional magnetic materials. Isosymmetric magnetoelastic FOMTs that do not perturb crystal symmetry are especially rare, and only a handful of material families, almost exclusively transition metal-based, are known to exhibit them. Yet, here we report a surprising isosymmetric FOMT in a rare-earth intermetallic, Eu₂In. What makes this transition in Eu₂In even more remarkable is that it is associated with a large latent heat and an exceptionally high magnetocaloric effect in low magnetic fields, but with tiny lattice discontinuities and negligible hysteresis. An active role of the Eu-5d and In-4p states and a rather unique electronic s

SUBMITTER: Guillou F 

PROVIDER: S-EPMC6062548 | biostudies-literature | 2018 Jul

REPOSITORIES: biostudies-literature