Crystal structure of a seven-coordinate manganese(II) complex with tris-(pyridin-2-ylmeth-yl)amine (TMPA).

ABSTRACT: Structural analysis of (acetato-κ²O,O')(methanol-κO)[tris-(pyridin-2-ylmeth-yl)amine-κ⁴N,N',N'',N''']manganese(II) tetraphenyl-borate, [Mn(C₂H₃O₂)(C₁₈H₁₈N₄)(CH₃OH)](C₂₄H₂₀B) or [Mn(TMPA)(Ac)(CH₃OH)]BPh₄ [TMPA = tris-(pyridin-2-ylmeth-yl)amine, Ac = acetate, BPh₄ = tetra-phenyl-borate] by single-crystal X-ray diffraction reveals a complex cation with tetra-dentate coordination of the tripodal TMPA ligand, bidentate coordination of the Ac ligand and monodentate coordination of the methanol ligand to a single Mn^II center, balanced in charge by the presence of a tetra-phenyl-borate a

SUBMITTER: Frey ST 

PROVIDER: S-EPMC6073006 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature