Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L₃-edge X-ray absorption spectroscopy.

ABSTRACT: The addition of various oxidants to the near-linear Sm(ii) complex [Sm(N^††)₂] (1), where N^†† is the bulky bis(triisopropylsilyl)amide ligand {N(SiⁱPr₃)₂}, afforded a family of heteroleptic three-coordinate Sm(iii) halide complexes, [Sm(N^††)₂(X)] (X = F, 2-F; Cl, 2-Cl; Br, 2-Br; I, 2-I). In addition, the trinuclear cluster [{Sm(N^††)}₃(μ₂-I)₃(μ₃-I)₂] (3), which formally contains one Sm(ii) and two Sm(iii) centres, was isolated during the synthesis of 2-I. Complexes 2-X are remarkably stable towards ligand redistribution, which is often a facile process for heteroleptic complexes of smaller monodentate ligands in lanthanide chemistry, includ

SUBMITTER: Goodwin CAP 

PROVIDER: S-EPMC6083822 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature