Quantification of Mercury Bioavailability for Methylation Using Diffusive Gradient in Thin-Film Samplers.

ABSTRACT: Mercury-contaminated sediment and water contain various Hg species, with a small fraction available for microbial conversion to the bioaccumulative neurotoxin monomethylmercury (MeHg). Quantification of this available Hg pool is needed to prioritize sites for risk management. This study compared the efficacy of diffusive gradient in thin-film (DGT) passive samplers to a thiol-based selective extraction method with glutathione (GSH) and conventional filtration (<0.2 μm) as indicators of Hg bioavailability. Anaerobic sediment slurry microcosms were amended with isotopically labeled inorganic Hg "endmembers" (dissolved Hg²⁺, Hg-humic acid, Hg-sorbed to FeS, HgS nanoparticles) with a known range of bioavailability and methylation potentials. Net MeHg production (expressed as percent

SUBMITTER: Ndu U 

PROVIDER: S-EPMC6085726 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature