Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands.

ABSTRACT: Treatment of both [CoCl( ^tBuPNP)] and [NiCl( ^tBuPNP)] ( ^tBuPNP = anion of 2,5-bis((di- tert-butylphosphino)methyl)pyrrole) with one equivalent of benzoquinone affords the corresponding chloride complexes containing a dehydrogenated PNP ligand, ^tBudPNP ( ^tBudPNP = anion of 2,5-bis((di- tert-butylphosphino)methylene)-2,5-dihydropyrrole). Dehydrogenation of PNP to dPNP results in minimal change to steric profile of the ligand but has important consequences for the resulting redox potentials of the metal complexes, resulting in the ability to isolate both [CoH( ^tBudPNP)] and [CoEt( ^tBudPNP)], which are more challenging (hydride) or not possible (ethyl) to prepare with the parent PNP ligand. Electrochemical measurement

SUBMITTER: Krishnan VM 

PROVIDER: S-EPMC6090532 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature