Unconventional Nickel Nitride Enriched with Nitrogen Vacancies as a High-Efficiency Electrocatalyst for Hydrogen Evolution.

ABSTRACT: Development of high-performance and cost-effective non-noble metal electrocatalysts is pivotal for the eco-friendly production of hydrogen through electrolysis and hydrogen energy applications. Herein, the synthesis of an unconventional nickel nitride nanostructure enriched with nitrogen vacancies (Ni3N1-x ) through plasma-enhanced nitridation of commercial Ni foam (NF) is reported. The self-supported Ni3N1-x /NF electrode can deliver a hydrogen evolution reaction (HER) activity competitive to commercial Pt/C catalyst in alkaline condition (i.e., an overpotential of 55 mV at 10 mA cm-2 and a Tafel slope of 54 mV dec-1), which is much superior to the stoichiometric Ni3N, and is the best among all nitride-based HER electrocatalysts in alkaline media reported thus far. Based on theoretical ca

SUBMITTER: Liu B 

PROVIDER: S-EPMC6097009 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature